You Reply: Thanks @Agree_dk, I managed to use a windows 10 Professional ISO image to boot my LPA and install a new copy of Windows on the original eMMC (preserving the copy of the old Windows clone on the NVMe). Interestingly this used the cloned UEFI partition on the NVMe disk even though it booted from the new Windows NVMe disk partition. I can confirm that the new install was automatically licensed too.
I then used a trial version of EasyUEFI to re-programme the UEFI partition to boot from the cloned Windows image on the NVMe partition to access the Windows version with all my programs and files.
I've now reformatted the eMMC disk as an additional disk.
One thing I did notice is that as the Windows updates come in, many of the drivers aren't available. I'm currently without WIFI, Bluetooth or Serial. It's not currently an issue for me as I'm using Gigabit Ethernet, but an updated resource kit for the LTA would be nice now.